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  <front>
    <journal-meta>
      <journal-title-group>
        <journal-title>Cosmological and Astrobiological Review: Journal for the Study of the Universe, Life and the Natural Sciences</journal-title>
      </journal-title-group>
      <issn pub-type="ppub">3126-3836</issn>
      <issn pub-type="epub">3126-3844</issn>
      <publisher>
        <publisher-name>SAPCRAA</publisher-name>
        <publisher-loc>Banja Luka, Bosnia and Herzegovina</publisher-loc>
      </publisher>
    </journal-meta>
    <article-meta>
      <article-id pub-id-type="publisher-id">1581</article-id>
      <article-id pub-id-type="doi">10.65932/CAR-2026-1-2</article-id>
      <title-group>
        <article-title>Hydrothermal vents versus the &quot;warm little pond&quot;: A comparative assessment of energy gradients in prebiotic synthesis and the origin of metabolism</article-title>
      </title-group>
      <contrib-group>
        <contrib contrib-type="author">
          <name>
            <surname>Knežević</surname>
            <given-names>Slaven</given-names>
          </name>
          <contrib-id contrib-id-type="orcid">https://orcid.org/0009-0002-7691-9526</contrib-id>
        </contrib>
      </contrib-group>
      <pub-date pub-type="epub">
        <day>29</day>
        <month>06</month>
        <year>2026</year>
      </pub-date>
      <volume>4</volume>
      <issue>1</issue>
      <fpage>30</fpage>
      <lpage>49</lpage>
      <self-uri xlink:href="https://sapcraa.com/article-preview/1581"/>
      <abstract>
        <p>The question of where and how the first living system arose remains the most contested issue in contemporary astrobiology, with the debate running for decades between two schools: the submarine alkaline hydrothermal vent hypothesis and the surface “warm little pond” (hot spring) hypothesis. This article does not attempt to declare a winner. Instead, it introduces a new analytical framework — the topology of the free-energy gradient — which reframes the entire debate as a distinction between a standing vectorial gradient (the chemiosmotic proton and redox gradient across a barrier, characteristic of vents) and a cyclic temporal gradient (alternating wetting and drying, characteristic of ponds). Alongside the framework, a measur-able Free-Energy Coupling Index (FECI) is proposed, scoring each environment along five dimensions: gradient persistence, vectorial coupling, spatial compartmentalization, cyclic condensation, and carbon–energy flux. A comparative synthesis of thermodynamic parame-ters from peer-reviewed literature (2019–2026) shows that vents achieve a high “metabolic bootstrap” score (FECI-M ≈ 0.82), whereas ponds achieve a high “replicative bootstrap” score (FECI-R ≈ 0.79). The central finding is that these two environments are not compet-ing but thermodynamically complementary along the metabolism→replication transition: the vent provides the continuous vectorial gradient required to bootstrap carbon and energy me-tabolism, while the pond provides the cyclic dehydration regime required for polymerization and encapsulation. The article concludes that the origin of life is tied not to a single location but to a sequence of gradient regimes, interpreted here within a morphology of the first cause (prauzrok).</p>
      </abstract>
      <kwd-group kwd-group-type="author">
        <kwd>abiogenesis</kwd>
        <kwd>alkaline hydrothermal vents</kwd>
        <kwd>warm little pond</kwd>
        <kwd>chemiosmosis</kwd>
        <kwd>free-energy gradient</kwd>
        <kwd>protometabolism</kwd>
        <kwd>first cause</kwd>
      </kwd-group>
    </article-meta>
  </front>
</article>
